Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 95
... carbon atom of the olefin not carrying a chlorine atom leads to formation of a normal adduct . When the addition of trichloromethyl radicals or bromine atoms occurs at a carbon atom carrying a chlorine atom the major products are CCI ...
... carbon atom of the olefin not carrying a chlorine atom leads to formation of a normal adduct . When the addition of trichloromethyl radicals or bromine atoms occurs at a carbon atom carrying a chlorine atom the major products are CCI ...
Page 129
... atom - atom polariza- bility of atoms i and j.5 For the systems considered by Dewar and Grisdale , differences between of and o ' were very small , and they favour the use of equation ( 3 ) . л carbon to which the side chain was ...
... atom - atom polariza- bility of atoms i and j.5 For the systems considered by Dewar and Grisdale , differences between of and o ' were very small , and they favour the use of equation ( 3 ) . л carbon to which the side chain was ...
Page 249
... carbon and hydrogen atoms , before fragmentation , in the molecular ion of benzene , and of the hydrogen atoms with ... atom undergoes negligible randomisation . Type 2 Photoelimination Reaction of Esters of Aromatic Carboxylic Acids.
... carbon and hydrogen atoms , before fragmentation , in the molecular ion of benzene , and of the hydrogen atoms with ... atom undergoes negligible randomisation . Type 2 Photoelimination Reaction of Esters of Aromatic Carboxylic Acids.
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values