Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 92
... chloride as the reaction proceeded . In previous experiments we had attributed this to slow coagulation of supersaturated silver chloride formed from small amounts of chloride ion always present in the hypochlorous acid ; but we have ...
... chloride as the reaction proceeded . In previous experiments we had attributed this to slow coagulation of supersaturated silver chloride formed from small amounts of chloride ion always present in the hypochlorous acid ; but we have ...
Page 663
... chloride ion . Here we describe studies of the reactivity of both mercury ( 11 ) and thallium ( III ) perchlorates and chlorides in the presence of varying concentrations of chloride ion , with the less highly charged ...
... chloride ion . Here we describe studies of the reactivity of both mercury ( 11 ) and thallium ( III ) perchlorates and chlorides in the presence of varying concentrations of chloride ion , with the less highly charged ...
Page 1090
... chloride was. 20.00 ° C Mean temp . Beckmann temp . Time ( min ) 1.230 = ( c = Correction 0.0036 ) ( min - 1 ) Total ... chloride was B.D.H. reagent grade ( pale yellow pieces only ) . Ethylene chloride ( B.D.H. reagent grade ) was re ...
... chloride was. 20.00 ° C Mean temp . Beckmann temp . Time ( min ) 1.230 = ( c = Correction 0.0036 ) ( min - 1 ) Total ... chloride was B.D.H. reagent grade ( pale yellow pieces only ) . Ethylene chloride ( B.D.H. reagent grade ) was re ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values