Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 95
... chlorine - substituted ethylenes has been studied in gas - phase experiments . Addition to a carbon atom of the olefin not carrying a chlorine atom leads to formation of a normal adduct . When the addition of trichloromethyl radicals or ...
... chlorine - substituted ethylenes has been studied in gas - phase experiments . Addition to a carbon atom of the olefin not carrying a chlorine atom leads to formation of a normal adduct . When the addition of trichloromethyl radicals or ...
Page 98
... chlorine elimination from chloroethyl radicals measured by Goldfinger and his co - workers 10 taken in conjunction with the known rates of CCl addition and bromine substitution sub- stantiate the idea that chlorine elimination would ...
... chlorine elimination from chloroethyl radicals measured by Goldfinger and his co - workers 10 taken in conjunction with the known rates of CCl addition and bromine substitution sub- stantiate the idea that chlorine elimination would ...
Page 582
... chlorine should also be produced . The fact that no molecular chlorine could be detected and that the reaction was found to be both surface - dependent and unaffected by propene leads us to suggest reactions ( 17 ) and ( 18 ) . ( 17 ) ...
... chlorine should also be produced . The fact that no molecular chlorine could be detected and that the reaction was found to be both surface - dependent and unaffected by propene leads us to suggest reactions ( 17 ) and ( 18 ) . ( 17 ) ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values