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Physical organic chemistry
Pyridonepyridol tautomerism in 2hydroxypyridines with 56annelated rings and oxygen at
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid
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acetic acid acid-catalysed activation added addition alcohol Amer amount analysis anion appears aqueous aromatic atom attack base benzene bond calculated carbon carbon tetrachloride Chem chloride compared compounds concentration constants containing correlation corresponding derived determined DISCUSSION effect electron energy epoxide equation esters ether exchange expected experimental experiments factor Figure followed formation formed give given greater hydrogen hydrolysis increase indicate initial involving isomer isotope ketone kinetic less lower measured mechanism methanol method methyl mixture molecule normal nucleophilic observed obtained occur oxide pairs peroxide plot positive possible prepared present proton radical range rate coefficients rate constants ratio reaction reactivity relative reported requires respectively ring shown shows similar sodium solution solvent spectra spectrum standard step structure studied substituted substrate suggested sulphuric t-butyl Table temperature transition values yield