Quarterly Journal of the Chemical Society of London, Volume 1 |
From inside the book
Results 1-3 of 73
Page 570
... dioxan are all greater than those in benzene , indicating hydrogen bonding between the hydrogen atom of the hydroxyl group and the oxygen atom of the dioxan molecule . Calculations have been made of the O - H bond moments necessary to ...
... dioxan are all greater than those in benzene , indicating hydrogen bonding between the hydrogen atom of the hydroxyl group and the oxygen atom of the dioxan molecule . Calculations have been made of the O - H bond moments necessary to ...
Page 859
... dioxan 0.0000 2.2095 1.42000 0.1952 2.2140 1.42036 0.3907 2.2175 1-42084 0.5876 2.2215 1.42134 0.7799 2.2253 1.42173 0.9729 2.2292 1.42210 1.1694 2.2334 1.42250 2.049 ; v = : 0.616 ; 0.0000 2.2725 1.49695 0.2295 2.2768 1.49723 0.4589 ...
... dioxan 0.0000 2.2095 1.42000 0.1952 2.2140 1.42036 0.3907 2.2175 1-42084 0.5876 2.2215 1.42134 0.7799 2.2253 1.42173 0.9729 2.2292 1.42210 1.1694 2.2334 1.42250 2.049 ; v = : 0.616 ; 0.0000 2.2725 1.49695 0.2295 2.2768 1.49723 0.4589 ...
Page 865
... dioxan TABLE 2 ( Continued ) 100w ε ND ( 24 ) N- ( 4 - Chlorobenzylidene ) -4 - hydroxyaniline in dioxan 0.0000 2.2127 1.41997 0.0971 2.2174 1.42014 0.1961 2.2228 1.42038 0.2949 2.2282 1.42074 0.3915 2.2330 1.42096 0.4864 2.2383 1.42109 ...
... dioxan TABLE 2 ( Continued ) 100w ε ND ( 24 ) N- ( 4 - Chlorobenzylidene ) -4 - hydroxyaniline in dioxan 0.0000 2.2127 1.41997 0.0971 2.2174 1.42014 0.1961 2.2228 1.42038 0.2949 2.2282 1.42074 0.3915 2.2330 1.42096 0.4864 2.2383 1.42109 ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
157 other sections not shown
Other editions - View all
Common terms and phrases
A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values