Quarterly Journal of the Chemical Society of London, Volume 1 |
From inside the book
Results 1-3 of 81
Page 160
... esters . = two cis - esters are very much smaller than those for the corresponding trans - esters , i.e. , AAH 5300 and 3500 cal mol - 1 , while the entropies of activation of the cis- esters have much larger negative entropies of ...
... esters . = two cis - esters are very much smaller than those for the corresponding trans - esters , i.e. , AAH 5300 and 3500 cal mol - 1 , while the entropies of activation of the cis- esters have much larger negative entropies of ...
Page 252
... esters such as ethyl p - cyanobenzoate , but not for simple alkyl benzoates . Aromatic esters of aromatic carboxylic acids undergo the photo - Fries rearrangement , 8 which has been studied in detail . Photolysis of the aromatic esters ...
... esters such as ethyl p - cyanobenzoate , but not for simple alkyl benzoates . Aromatic esters of aromatic carboxylic acids undergo the photo - Fries rearrangement , 8 which has been studied in detail . Photolysis of the aromatic esters ...
Page 1168
... esters have previously been studied in some detail , no similar study of phosphate esters containing olefinic unsaturation has been published . The hydrolytic stability of dimethylallyl and isopentenyl pyrophos- phates is of ...
... esters have previously been studied in some detail , no similar study of phosphate esters containing olefinic unsaturation has been published . The hydrolytic stability of dimethylallyl and isopentenyl pyrophos- phates is of ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
157 other sections not shown
Other editions - View all
Common terms and phrases
A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values