Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 168
... given in ref . 7 . ( 8 ) ( 9 ) The values of overall t , overall ∞ , Q , and R on the final cycle for each ' starting set ' are given in Table 3. For a consistent set of phases one would expect a and t to be high and Q and R to be low ...
... given in ref . 7 . ( 8 ) ( 9 ) The values of overall t , overall ∞ , Q , and R on the final cycle for each ' starting set ' are given in Table 3. For a consistent set of phases one would expect a and t to be high and Q and R to be low ...
Page 306
... given in ref . 37 . TABLE 9 Relative rate coefficients for the reaction of trimethylamine with the nitrobenzyl chlorides , and standard free energies of transfer ( on the mole fraction scale ) from ethyl benzoate to other solvents of ...
... given in ref . 37 . TABLE 9 Relative rate coefficients for the reaction of trimethylamine with the nitrobenzyl chlorides , and standard free energies of transfer ( on the mole fraction scale ) from ethyl benzoate to other solvents of ...
Page 1223
... given reaction system . Of course one does thereby obtain a better fit and an expression of wider applicability . In practice m is often taken as 2 , the factors being equated with polar and resonance contributions to AAH . The ...
... given reaction system . Of course one does thereby obtain a better fit and an expression of wider applicability . In practice m is often taken as 2 , the factors being equated with polar and resonance contributions to AAH . The ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values