Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 58
... mmHg ( lit. , 38 51-52 ° at 1 mmHg ) . m- ( 1,2 - Epoxyethyl ) toluene . - m - Methylacetophenone , pre- pared from m - toluic acid by Gilman and Nelson's method , 39 was converted by Laird and Parker's 2d method into the epoxide ...
... mmHg ( lit. , 38 51-52 ° at 1 mmHg ) . m- ( 1,2 - Epoxyethyl ) toluene . - m - Methylacetophenone , pre- pared from m - toluic acid by Gilman and Nelson's method , 39 was converted by Laird and Parker's 2d method into the epoxide ...
Page 301
... ( mmHg / ( mmHg / Solvent M ) " N ) Y Hexane 248 1884 1.147 Ether 349 3332 2.029 Benzene 172 1923 1.171 Ethyl acetate 220 2233 1.360 n - Propanol 39.4 524 0.319 -695 3 - Methylbutanol 48.3 441 0.269 Ethanol 39.5 673 0.410 - -780 -545 ...
... ( mmHg / ( mmHg / Solvent M ) " N ) Y Hexane 248 1884 1.147 Ether 349 3332 2.029 Benzene 172 1923 1.171 Ethyl acetate 220 2233 1.360 n - Propanol 39.4 524 0.319 -695 3 - Methylbutanol 48.3 441 0.269 Ethanol 39.5 673 0.410 - -780 -545 ...
Page 422
... mmHg ; and di- ( 4 - chlorophenyl ) amine , m.p. 77 ° . Diphenylamine ( Hopkins and Williams ) had m.p. 54 ° . These ... mmHg ; tri - m - tolyl phosphite , b.p. 216 ° / 5.5 mmHg ; tri - p - tolyl phosphite , b.p. 230 ° / 2.5 mmHg ...
... mmHg ; and di- ( 4 - chlorophenyl ) amine , m.p. 77 ° . Diphenylamine ( Hopkins and Williams ) had m.p. 54 ° . These ... mmHg ; tri - m - tolyl phosphite , b.p. 216 ° / 5.5 mmHg ; tri - p - tolyl phosphite , b.p. 230 ° / 2.5 mmHg ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values