Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 68
... mol - 1 , AS1 in cal mol - 1 K - 1 , k , in 1 mol - 1 s - 1 . † Values in parentheses are the molar solubility of hydrogen chloride in one mol of solvent at 10 ° with a total pressure of one atmosphere ( L - value ) ( W. Gerrard and ...
... mol - 1 , AS1 in cal mol - 1 K - 1 , k , in 1 mol - 1 s - 1 . † Values in parentheses are the molar solubility of hydrogen chloride in one mol of solvent at 10 ° with a total pressure of one atmosphere ( L - value ) ( W. Gerrard and ...
Page 315
... 1 - phenyl - 2 - trimethylsilylacetylene with sodium , potassium , and caesium as gegenions in tetrahydrofuran have ... mol - 1 s - 1 , AG ‡ = 13.5 kcal mol - 1 , AH = 6.3 kcal mol - 1 , AS = -33.8 cal mol - 1 K - 1 : Cs + as gegenion ...
... 1 - phenyl - 2 - trimethylsilylacetylene with sodium , potassium , and caesium as gegenions in tetrahydrofuran have ... mol - 1 s - 1 , AG ‡ = 13.5 kcal mol - 1 , AH = 6.3 kcal mol - 1 , AS = -33.8 cal mol - 1 K - 1 : Cs + as gegenion ...
Page 558
... 1 Specific rate coefficients for the reaction of NR1 , N'R2 di- substituted 2 - chlorobenzimidazolium perchlorates ... mol 1-1 2.04 4.80 9.90 17.8 49-8 Ho 2.76 2.31 2.03 1.72 1.11 [ LICIO J / mol 1 - 1 10k / 1 mol - 1 s - 1 27.5 10.7 ...
... 1 Specific rate coefficients for the reaction of NR1 , N'R2 di- substituted 2 - chlorobenzimidazolium perchlorates ... mol 1-1 2.04 4.80 9.90 17.8 49-8 Ho 2.76 2.31 2.03 1.72 1.11 [ LICIO J / mol 1 - 1 10k / 1 mol - 1 s - 1 27.5 10.7 ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values