Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 86
... olefin , where such differentiation is possible ( Table , Compounds 3 , 4 , 11 , 12 , 14 , and 15 ) , was obtained in almost all of the success- ful reactions involving both symmetric and non - sym- metric olefins ; exceptions are also ...
... olefin , where such differentiation is possible ( Table , Compounds 3 , 4 , 11 , 12 , 14 , and 15 ) , was obtained in almost all of the success- ful reactions involving both symmetric and non - sym- metric olefins ; exceptions are also ...
Page 89
... olefin appears im- perative for the addition of the elements HOBr by the dimethyl sulphoxide procedure . Finally , whereas the addition of hydrochloric acid to , for example , 3,3 - dimethylbut - 1 - ene ( Table , Compound 21 ) yields ...
... olefin appears im- perative for the addition of the elements HOBr by the dimethyl sulphoxide procedure . Finally , whereas the addition of hydrochloric acid to , for example , 3,3 - dimethylbut - 1 - ene ( Table , Compound 21 ) yields ...
Page 95
... Olefin CX2 = CXCI TABLE 1 Photolysis of CCl ,. • THE orientation of trichloromethyl radical attack on unsymmetrical fluoro - olefins , and the relative reactivity of the fluorine substituted carbon atoms is now well established.2 ...
... Olefin CX2 = CXCI TABLE 1 Photolysis of CCl ,. • THE orientation of trichloromethyl radical attack on unsymmetrical fluoro - olefins , and the relative reactivity of the fluorine substituted carbon atoms is now well established.2 ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values