Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 259
... parameters in the isotropic refinement ; this process is not justified in the anisotropic case 19 owing to high correlations between scale - factors and anisotropic thermal parameters . All further refinement was performed using the ...
... parameters in the isotropic refinement ; this process is not justified in the anisotropic case 19 owing to high correlations between scale - factors and anisotropic thermal parameters . All further refinement was performed using the ...
Page 460
... parameters has been made covering spectroscopic , rate , and equilibrium data . Various multiparameter equations have been tested by use of linear combinations of existing empirical solvent parameters . The most generally successful ...
... parameters has been made covering spectroscopic , rate , and equilibrium data . Various multiparameter equations have been tested by use of linear combinations of existing empirical solvent parameters . The most generally successful ...
Page 535
... parameters for their sublimation ( Table 2 ) and solution ( Table 3 ) . TABLE 6 Thermodynamic parameters for the hydration of four phenols at 25 ° C ΔΗ . kcal mol - 1 ΔΗ , kcal mol - 1 AH , " kcal mol - 1 AG , Phenol 0.88 -15.77 8.87 ...
... parameters for their sublimation ( Table 2 ) and solution ( Table 3 ) . TABLE 6 Thermodynamic parameters for the hydration of four phenols at 25 ° C ΔΗ . kcal mol - 1 ΔΗ , kcal mol - 1 AH , " kcal mol - 1 AG , Phenol 0.88 -15.77 8.87 ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values