Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 511
... rate coefficients merely refer to the rate of reaction through the various transition states which are defined by the number of chloride ions associated with the cation ( I ) , e.g. k2 represents the rate of re- action through a ...
... rate coefficients merely refer to the rate of reaction through the various transition states which are defined by the number of chloride ions associated with the cation ( I ) , e.g. k2 represents the rate of re- action through a ...
Page 665
... rate coefficients for the reaction of the 3 - pyridiniomethyldicarb- onyl -- cyclopentadienyliron ion are also shown ... coefficients shown in Table 4 are dependent upon the accuracy of the stability constants used in the derivation 14 ...
... rate coefficients for the reaction of the 3 - pyridiniomethyldicarb- onyl -- cyclopentadienyliron ion are also shown ... coefficients shown in Table 4 are dependent upon the accuracy of the stability constants used in the derivation 14 ...
Page 666
... rate coefficients are therefore likely to represent electrophilic reactivities for attack of the 3 - Hpy CH2Fe ( π - CH ( CO ) 2 + M log10 * 2 3.0 2.0- 1.0- 0 7 6 5 ง 3 -1.0- 2 -2.0- -3.0- -40- -50 M MCL MCI2 2 MCI 3 MCI , log 10K ...
... rate coefficients are therefore likely to represent electrophilic reactivities for attack of the 3 - Hpy CH2Fe ( π - CH ( CO ) 2 + M log10 * 2 3.0 2.0- 1.0- 0 7 6 5 ง 3 -1.0- 2 -2.0- -3.0- -40- -50 M MCL MCI2 2 MCI 3 MCI , log 10K ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values