Quarterly Journal of the Chemical Society of London, Volume 1 |
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Results 1-3 of 79
Page 70
... constant for the abnormal attack is identical with that previously given for the negative polar reaction constants obtained for the acid- catalysed solvolysis of the substituted ( 1,2 ... rate of reaction 70 J. Chem . Soc . ( B ) , 1971.
... constant for the abnormal attack is identical with that previously given for the negative polar reaction constants obtained for the acid- catalysed solvolysis of the substituted ( 1,2 ... rate of reaction 70 J. Chem . Soc . ( B ) , 1971.
Page 71
... reaction , L ( + ) - 1 - methoxy - 2 - phenylethanol , has been synthesised . Analysis of the product of acid ... constant . As the observed polar reaction constant is negative , the effect of substituents on the initial equilibrium step ...
... reaction , L ( + ) - 1 - methoxy - 2 - phenylethanol , has been synthesised . Analysis of the product of acid ... constant . As the observed polar reaction constant is negative , the effect of substituents on the initial equilibrium step ...
Page 501
... reaction constant usually varies inversely with the reaction temperature , 13 the discrepancy between the results is too large to be ex- plained by this artefact . The earlier work was based on only four substituents and the value of ...
... reaction constant usually varies inversely with the reaction temperature , 13 the discrepancy between the results is too large to be ex- plained by this artefact . The earlier work was based on only four substituents and the value of ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
157 other sections not shown
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Common terms and phrases
A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values
Bibliographic information
| Title | Quarterly Journal of the Chemical Society of London, Volume 1 |
| Author | Chemical Society (Great Britain) |
| Contributor | Royal Society of Chemistry (Great Britain) |
| Published | 1971 |
| Original from | the University of Michigan |
| Digitized | 6 Jun 2011 |
| Export Citation | BiBTeX EndNote RefMan |