Quarterly Journal of the Chemical Society of London, Volume 1 |
From inside the book
Results 1-3 of 85
Page 79
... reactivity of the a - position is always decreased by a similar factor and the reactivity of the B - position is ( with two exceptions ) increased , in both systems . In recent years many quantitative data have accumu- lated 23 on the ...
... reactivity of the a - position is always decreased by a similar factor and the reactivity of the B - position is ( with two exceptions ) increased , in both systems . In recent years many quantitative data have accumu- lated 23 on the ...
Page 537
... reactivity of each 2 - position was closely similar ; the small differences in reactivity order were attributed to different demands for resonance in the two reactions . The purpose of the present work was to obtain additional data ...
... reactivity of each 2 - position was closely similar ; the small differences in reactivity order were attributed to different demands for resonance in the two reactions . The purpose of the present work was to obtain additional data ...
Page 717
... reactivity of benzotri- fluoride as determined in aqueous sulphuric acid by Coombes , Moodie , and Schofield.12 ... reactivity of this substrate relative to benzene was calculated by combining the data on the reactivity relative to ...
... reactivity of benzotri- fluoride as determined in aqueous sulphuric acid by Coombes , Moodie , and Schofield.12 ... reactivity of this substrate relative to benzene was calculated by combining the data on the reactivity relative to ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
151 other sections not shown
Other editions - View all
Common terms and phrases
A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values