Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 537
... reactivity of each 2 - position was closely similar ; the small differences in reactivity order were attributed to different demands for resonance in the two reactions . The purpose of the present work was to obtain additional data ...
... reactivity of each 2 - position was closely similar ; the small differences in reactivity order were attributed to different demands for resonance in the two reactions . The purpose of the present work was to obtain additional data ...
Page 717
... reactivity thereby obtained is ' anomalous ' . This value is listed in Table 2 . benzotrichloride and benzene has then been calculated from the corresponding relative reactivity of benzotri- fluoride as determined in aqueous sulphuric ...
... reactivity thereby obtained is ' anomalous ' . This value is listed in Table 2 . benzotrichloride and benzene has then been calculated from the corresponding relative reactivity of benzotri- fluoride as determined in aqueous sulphuric ...
Page 1221
Chemical Society (Great Britain). Reactivity Parameters and Aromatic Systems . Part III.1 Reactivity Re- lationships , and their Application to Substituent Effects in Aromatic Systems By K. C. C. Bancroft * and G. R. Howe , School of ...
Chemical Society (Great Britain). Reactivity Parameters and Aromatic Systems . Part III.1 Reactivity Re- lationships , and their Application to Substituent Effects in Aromatic Systems By K. C. C. Bancroft * and G. R. Howe , School of ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values