Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 539
... reported here forms part of a continuing study on the thermal decomposition of strained - ring hydro- carbons . Many of these compounds undergo valence- bond isomerizations , which are good examples of true unimolecular reactions ...
... reported here forms part of a continuing study on the thermal decomposition of strained - ring hydro- carbons . Many of these compounds undergo valence- bond isomerizations , which are good examples of true unimolecular reactions ...
Page 1115
... reported 4 for a - phenoxyisobutyraldehyde . In contrast , for gly- ceraldehyde the main product of controlled - potential electrolysis by means of a mercury pool electrode was reported to be glycerol , which indicates a preferential ...
... reported 4 for a - phenoxyisobutyraldehyde . In contrast , for gly- ceraldehyde the main product of controlled - potential electrolysis by means of a mercury pool electrode was reported to be glycerol , which indicates a preferential ...
Page 1179
... reported 10 for reaction ( 3 ) gives equation ( 10 ) . This R2 = 10 ( 11.33 ± 0 · 8 ) exp ( 12,120 2700 ) / RT cm3 mol - 1 s - 1 ( 10 ) value for E , is in good agreement with that reported by Gozzo and Patrick 4 ( 15 ± 5 kcal mol - 1 ) ...
... reported 10 for reaction ( 3 ) gives equation ( 10 ) . This R2 = 10 ( 11.33 ± 0 · 8 ) exp ( 12,120 2700 ) / RT cm3 mol - 1 s - 1 ( 10 ) value for E , is in good agreement with that reported by Gozzo and Patrick 4 ( 15 ± 5 kcal mol - 1 ) ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values