Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 92
... silver perchlorate are p - xylene , 0.95 ; m - xylene , 0-94 ; triphenyl- ene , 0.95 ; and naphthalene , 0.95 . With 0.001M - silver perchlorate , the corresponding values are p - xylene , 1.02 ; m - xylene , 0.91 ; mesitylene , 0.90 ...
... silver perchlorate are p - xylene , 0.95 ; m - xylene , 0-94 ; triphenyl- ene , 0.95 ; and naphthalene , 0.95 . With 0.001M - silver perchlorate , the corresponding values are p - xylene , 1.02 ; m - xylene , 0.91 ; mesitylene , 0.90 ...
Page 93
... silver perchlorate to reduce the concentration of chlorine to negligible proportions . Chlorination by the latter ... perchlorate for all the substrates except mesitylene , the most rapidly reacting compound we examined . The rate ...
... silver perchlorate to reduce the concentration of chlorine to negligible proportions . Chlorination by the latter ... perchlorate for all the substrates except mesitylene , the most rapidly reacting compound we examined . The rate ...
Page 94
... silver chloride is not visible to the unaided eye . The main reaction accounting for the disappearance of hypochlorous acid , both in the presence and in the absence of silver perchlorate , gives chloro - substituted aromatic compounds ...
... silver chloride is not visible to the unaided eye . The main reaction accounting for the disappearance of hypochlorous acid , both in the presence and in the absence of silver perchlorate , gives chloro - substituted aromatic compounds ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values