Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 43
Chemical Society (Great Britain). mena observed in the cases of sodium hydroxide in water and sodium methoxide in methanol , can be attributed in part to the greater solvation of the lyate ion than that of the indicator base , as a ...
Chemical Society (Great Britain). mena observed in the cases of sodium hydroxide in water and sodium methoxide in methanol , can be attributed in part to the greater solvation of the lyate ion than that of the indicator base , as a ...
Page 272
... sodium carbonate solution and then with water . After being dried ( CaCl2 ) it was fractionated through a 1 m . column , and had b.p. 107-7 ° ( lit. , 30 107-3 ° ) , n , 25 1.5091 ( lit. , 30 m , 20 , 1.5136 ) . 1,2 - Dibromoethane ...
... sodium carbonate solution and then with water . After being dried ( CaCl2 ) it was fractionated through a 1 m . column , and had b.p. 107-7 ° ( lit. , 30 107-3 ° ) , n , 25 1.5091 ( lit. , 30 m , 20 , 1.5136 ) . 1,2 - Dibromoethane ...
Page 627
... sodium and potassium salts were pure commercial specimens and were used without further treatment . The barium salt was prepared from AnalaR barium hydroxide and sodium rhodizonate and the lithium salt by reaction of pure lithium ...
... sodium and potassium salts were pure commercial specimens and were used without further treatment . The barium salt was prepared from AnalaR barium hydroxide and sodium rhodizonate and the lithium salt by reaction of pure lithium ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values