Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 341
... studied are reduced by water vapour present in the mass spectrometer and that this reaction provides a mass spectral method for distinguishing between 1,2- and 1,4 - naphthaquinones . No simple relationship is found to exist between the ...
... studied are reduced by water vapour present in the mass spectrometer and that this reaction provides a mass spectral method for distinguishing between 1,2- and 1,4 - naphthaquinones . No simple relationship is found to exist between the ...
Page 483
... studied at various temperatures . The inter- pretation of the kinetic data by different mechanistic criteria leads to the conclusion that the acid hydrolyses occur , in the most general case , by two simultaneous mechanisms , A1 and A2 ...
... studied at various temperatures . The inter- pretation of the kinetic data by different mechanistic criteria leads to the conclusion that the acid hydrolyses occur , in the most general case , by two simultaneous mechanisms , A1 and A2 ...
Page 646
... studied the reaction of ethoxy- carbonylcarbene with n - hexadecane and n - docosane . The reactions of carbenes with various substrates have been widely studied , 1-5 yet little work has been done on those with high molecular weight ...
... studied the reaction of ethoxy- carbonylcarbene with n - hexadecane and n - docosane . The reactions of carbenes with various substrates have been widely studied , 1-5 yet little work has been done on those with high molecular weight ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values