Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 98
Chemical Society (Great Britain). photochemical chlorination of halogenoalkanes was suggested by Rust and Vaughan , 8 and a chlorine elimin- ation mechanism was also suggested by Nesmayanov et al . to account for the formation of 1,1,4,4 ...
Chemical Society (Great Britain). photochemical chlorination of halogenoalkanes was suggested by Rust and Vaughan , 8 and a chlorine elimin- ation mechanism was also suggested by Nesmayanov et al . to account for the formation of 1,1,4,4 ...
Page 433
... suggest the free - radical mechanism shown in the Scheme . Steps ( 1 ) - ( 6 ) are typical of those suggested for the autoxidation of trialkyl phosphites.13 Equation ( 7 ) was used by Emerson and Rees 18 to explain the stituent ...
... suggest the free - radical mechanism shown in the Scheme . Steps ( 1 ) - ( 6 ) are typical of those suggested for the autoxidation of trialkyl phosphites.13 Equation ( 7 ) was used by Emerson and Rees 18 to explain the stituent ...
Page 577
... suggested by Barton and Howlett is discussed and modified to account for the experimental observations . The pressure - time curves obtained from experiments at high surface : volume ratio indicate that under these conditions the ...
... suggested by Barton and Howlett is discussed and modified to account for the experimental observations . The pressure - time curves obtained from experiments at high surface : volume ratio indicate that under these conditions the ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values