Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 157
... trans - H 32-34 32 11 Synthetic method * 1 . trans - 4 ' - F 85-86 1 a trans - 4 ' - Cl 81-82 14 trans - 4 ' - Br 75-76 77 12 trans - 4 ' - I 102-103 trans - 4 ' - Me 45-47 la trans - 4 ' - OMe 70-71 71-72 10 16 trans - 3 ' - NO2 102 ...
... trans - H 32-34 32 11 Synthetic method * 1 . trans - 4 ' - F 85-86 1 a trans - 4 ' - Cl 81-82 14 trans - 4 ' - Br 75-76 77 12 trans - 4 ' - I 102-103 trans - 4 ' - Me 45-47 la trans - 4 ' - OMe 70-71 71-72 10 16 trans - 3 ' - NO2 102 ...
Page 158
... trans - 4 ' - F C11H , FO 63.6 4.3 23.1 63.4 4.4 23.3 trans - 4 ' - Cl C11H , CIO 58.8 4.0 21.4 15.8 ( Cl ) 58.7 3.9 15.6 ( Cl ) trans - 4 ' - I CHIO , 41.3 2.8 15.0 41-7 2.9 15.1 trans - 4 ' - Me CH12O3 70.6 5.9 23.5 70-7 6.0 23-7 trans ...
... trans - 4 ' - F C11H , FO 63.6 4.3 23.1 63.4 4.4 23.3 trans - 4 ' - Cl C11H , CIO 58.8 4.0 21.4 15.8 ( Cl ) 58.7 3.9 15.6 ( Cl ) trans - 4 ' - I CHIO , 41.3 2.8 15.0 41-7 2.9 15.1 trans - 4 ' - Me CH12O3 70.6 5.9 23.5 70-7 6.0 23-7 trans ...
Page 1328
... trans - 4 - phenylcyclohexylamine was obtained by minor modification of published procedures : p - phenylphenol was hydrogenated to mixed cis- and trans - 4 - phenyl- cyclohexanol , and the mixture oxidised to 4 - phenyl- cyclohexanone ...
... trans - 4 - phenylcyclohexylamine was obtained by minor modification of published procedures : p - phenylphenol was hydrogenated to mixed cis- and trans - 4 - phenyl- cyclohexanol , and the mixture oxidised to 4 - phenyl- cyclohexanone ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values