Journal of the Chemical Society, Part 3Chemical Society., 1949 |
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Results 1-3 of 79
Page 1951
... formation of the benzoyl compound ( III ) is unusual when a tertiary acid halide reacts with benzene . The only instances which have been encountered by the present authors are the formation of trichloroacetophenone from trichloroacetyl ...
... formation of the benzoyl compound ( III ) is unusual when a tertiary acid halide reacts with benzene . The only instances which have been encountered by the present authors are the formation of trichloroacetophenone from trichloroacetyl ...
Page 1963
... formation of the carbonium complex may follow alternative paths . When a suitable aromatic compound is present , a reaction analogous to ketone formation results , i.e. , there is an electrophilic attack by a cation , in this case the ...
... formation of the carbonium complex may follow alternative paths . When a suitable aromatic compound is present , a reaction analogous to ketone formation results , i.e. , there is an electrophilic attack by a cation , in this case the ...
Page 1978
... formation ( S. D. Ross , J. Amer . Chem . Soc . , 1947 , 69 , 2982 ) . Et , N.CH , CHMeCl →→ [ Et , NXH , ( III . ) CHMe ( IV . ) Et , NCHMe.CH , OH ( V. ) There is no such evidence for the existence of an ion of this type during the ...
... formation ( S. D. Ross , J. Amer . Chem . Soc . , 1947 , 69 , 2982 ) . Et , N.CH , CHMeCl →→ [ Et , NXH , ( III . ) CHMe ( IV . ) Et , NCHMe.CH , OH ( V. ) There is no such evidence for the existence of an ion of this type during the ...
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Common terms and phrases
acetic acid acetic anhydride acetone acetyl added admixture alkaline alkyl aluminium chloride Amer ammonia aqueous solution atoms barium benzene boiling bromine Calc carbinol carbon catalyst Chem Chim chloroform colourless needles compound concentrated condensation cooled crystals cyclohexene decomp derivatives dilute dioxan dissolved distilled dithizone dried equiv ester ethanol ethyl acetate ethyl alcohol ethylene evaporated EXPERIMENTAL filtered filtrate formed Found fraction gave give heated under reflux hydrocarbon hydrochloric acid hydrogen chloride hydrolysis iodide ions isolated ketone Light absorption light petroleum b. p. method methyl mixed m. p. mixture molecule obtained oxide phenyl plates potassium hydroxide precipitated prepared pressure prisms pyridine Q-enzyme R₁ R₂ reaction reagent reduced removed requires residue room temperature salt semicarbazone separated sodium hydroxide solid soluble solvent specimen structure substance sulphate sulphone sulphuric acid synthesis Table unsaturated washed yield