Journal of the Chemical SocietyThe Society., 1951 |
From inside the book
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Page 11
... ketone and phenylmagnesium bromide give precipitates of complexes , which , when treated with water , regenerate the respective ketones ; and secondly , that excesses of 100-300 % of phenyl magnesium bromide are required to prepare the ...
... ketone and phenylmagnesium bromide give precipitates of complexes , which , when treated with water , regenerate the respective ketones ; and secondly , that excesses of 100-300 % of phenyl magnesium bromide are required to prepare the ...
Page 84
... ketone , di - n - propyl ketone , isobutyl methyl ketone , diisobutyl ketone , cyclopentanone , cyclohexanone , a variety of esters with a five - atom chain , and all alcohols so far tested . The bases which yield crystalline complexes ...
... ketone , di - n - propyl ketone , isobutyl methyl ketone , diisobutyl ketone , cyclopentanone , cyclohexanone , a variety of esters with a five - atom chain , and all alcohols so far tested . The bases which yield crystalline complexes ...
Page 788
... ketone ( IV ) by the present method , there is no formation of the isomeric ketone , 1 : 3 - endoethylene - 4 - keto - 1 : 23 : 4 - tetrahydronaphthalene , which is produced by reaction of benzene with cyclopent - 1 - enecarboxylic acid ...
... ketone ( IV ) by the present method , there is no formation of the isomeric ketone , 1 : 3 - endoethylene - 4 - keto - 1 : 23 : 4 - tetrahydronaphthalene , which is produced by reaction of benzene with cyclopent - 1 - enecarboxylic acid ...
Contents
Synthesis of 8Substituted Pteridine Derivatives | 3 |
A Contribution to the Chemistry of the Sesquiterpene Humulene | 22 |
Studies in Coordination Chemistry Part VII Complexes of Univalent Copper | 38 |
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Common terms and phrases
absorption acetic anhydride acetone acridine added alcohol alkaline Amer anhydride atoms benzene boiling bromine Calc carbinol carbon cations cell Chem chloroform colourless complex compound concentration constant crystallised crystals curve D.Sc decomp decomposition derivatives diamidide dilute dissolved distilled dried electrode equation ester ethanol ether ethyl alcohol evaporated EXPERIMENTAL extracted filtered formation formed Found fraction gave give m. p. glacial acetic acid Grignard reagent heated hydrochloric acid hydrogen chloride hydrogen phthalate hydrolysis iodide isolated ketone light petroleum b. p. m. p. and mixed method methyl minutes mixed m. p. mixture molecular molecules morolic needles obtained olefin oxidation peroxide phenyl phosphate phthalate potassium hydroxide precipitate prepared prisms pteridine pyridine reaction reduction refluxed requires residue room temperature salt saturated separated sodium hydroxide solid soluble solvent sulphate sulphuric acid Table titration trifluoroiodomethane values washed yellow yield