Quarterly Journal of the Chemical Society of London, Part 5, Pages 5005-6079 |
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Page 5022
... concentration is increased . Fig . 1 shows typical plots of rate against optical density at three hydrogen peroxide concentrations , and Fig . 2 shows the variation in the slope of such lines against the water 0.7 ( ml./min . ) Rate 0.6 ...
... concentration is increased . Fig . 1 shows typical plots of rate against optical density at three hydrogen peroxide concentrations , and Fig . 2 shows the variation in the slope of such lines against the water 0.7 ( ml./min . ) Rate 0.6 ...
Page 5025
... concentration throughout was 2 × 10 ̃3м . A comparatively narrow range of hydrogen peroxide concentrations was studied ( 0 · 55—0 · 75 mole fraction ) . At concentrations below 0.55 , catalysis was too slow to be measured , and above 0 ...
... concentration throughout was 2 × 10 ̃3м . A comparatively narrow range of hydrogen peroxide concentrations was studied ( 0 · 55—0 · 75 mole fraction ) . At concentrations below 0.55 , catalysis was too slow to be measured , and above 0 ...
Page 5026
... concentration , and the values of K ' calculated . Values of K ' so obtained are listed in Table 2. At every solvent concentration , K ' was reasonably independent of the hydrogen - ion concentration . It will be seen that K ' changes ...
... concentration , and the values of K ' calculated . Values of K ' so obtained are listed in Table 2. At every solvent concentration , K ' was reasonably independent of the hydrogen - ion concentration . It will be seen that K ' changes ...
Contents
Peroxycomplexes of inorganic ions in hydrogen peroxidewater mixtures Part | 5020 |
Pyrazine metal complexes Part III | 5042 |
The reaction between ethane and oxygen at 600630 | 5106 |
103 other sections not shown
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absorption acetic acid acetic anhydride acetone added alcohol aldehyde alkaline alumina Amax Amer anhydride aromatic atoms bands benzene benzyl boiling bond bromide Calc carbonate carboxylic Chem chloride chloroform chromatography cm.¹ complexes compound concentration constants crystallised crystals decomp decomposition derivative dilute dioxan distilled dried electron Elution ester ethanol ether ethyl acetate ethylene evaporated extracted filtered filtrate formation formed Found fraction gave H₂O heated hydration hydrogen hydrolysis infrared infrared spectrum iodide isomer isomeric ketone light petroleum lithium aluminium hydride m. p. and mixed methyl mixed m. p. mixture mole molecule needles nitric nitric oxide nitrogen observed obtained oxide ozonolysis peroxide phenyl potassium prepared proton pyridine radicals reaction refluxed requires residue resonance room temperature salt sodium hydroxide sodium methoxide solid solution solvent spectra steric structure substituent sulphate Table ultraviolet values Vmax washed yield