Journal of the Chemical SocietyThe Society., 1949 |
From inside the book
Results 1-3 of 81
Page 107
... hydrolysis to hypochlorous acid and partly by direct interaction with the phenoxide ion . No direct reaction with the un - ionised phenol was appreciable in a range of phenols . The rate of hydrolysis of N - chloroacetanilide is ...
... hydrolysis to hypochlorous acid and partly by direct interaction with the phenoxide ion . No direct reaction with the un - ionised phenol was appreciable in a range of phenols . The rate of hydrolysis of N - chloroacetanilide is ...
Page 187
... hydrolysis by the addition of chloride ions supports this mechanism ( Table III ) . FIG . 1 . 1.6 1.4 1-2 1.0 Log 1 / ( 1 - fraction of base hydrolysed at 37 ° ) . 0-8 0.6 0.4 5 80.2 0 0 20 40 60 80 Time , hours . 100 120 1. NN - Di ...
... hydrolysis by the addition of chloride ions supports this mechanism ( Table III ) . FIG . 1 . 1.6 1.4 1-2 1.0 Log 1 / ( 1 - fraction of base hydrolysed at 37 ° ) . 0-8 0.6 0.4 5 80.2 0 0 20 40 60 80 Time , hours . 100 120 1. NN - Di ...
Page 188
... hydrolysis also supports an Syl mechanism . Table IV shows that the variation in velocity of reaction in aqueous ... hydrolysis of some Compound . NN - Di- ( 2 - chloroethyl ) - aniline o - toluidine m - toluidine TABLE IV . Volume ...
... hydrolysis also supports an Syl mechanism . Table IV shows that the variation in velocity of reaction in aqueous ... hydrolysis of some Compound . NN - Di- ( 2 - chloroethyl ) - aniline o - toluidine m - toluidine TABLE IV . Volume ...
Other editions - View all
Common terms and phrases
absorption acetic acid acetic anhydride acetone added addition alkaline aluminium aluminium chloride Amer ammonia anhydride atom benzene boiling bond bromide Calc carbon catalyst CH₂ Chem chloroform colourless needles compound concentrated condensation cooled crystallised crystals curve cyanide D.Sc decomp decomposition derivatives dilute dissolved distilled disulphide dried ester ethyl acetate ethyl alcohol ethylene evaporated extracted with ether filtered filtrate formed Found fraction gave give m. p. heated hydrochloric acid hydrogen chloride hydrolysis iodide isolated ketone kojic acid light petroleum b. p. m. p. and mixed methanol method mixed m. p. mixture molecule obtained oxide phenyl picrate potassium hydroxide precipitated prepared prisms pyridine reaction reagent reduced pressure refluxed requires residue room temperature salt separated sodium hydroxide solid soluble solution solvent stirred structure sulphate sulphide sulphone sulphuric acid thionyl chloride washed yellow yield