Quarterly Journal of the Chemical Society of London, Volume 21 |
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Results 1-3 of 82
Page 3598
... give the crude product ( 21.6 g ) , which was recrystallised from benzene - light petroleum ( b.p. 60-80 ° ) to give the ketone ( VII ) , m.p. 114.5-116 ° ( Found : C , 59.1 ; H , 2.5 . C1H , FO requires C , 58 · 75 ; H , 2 · 5 ...
... give the crude product ( 21.6 g ) , which was recrystallised from benzene - light petroleum ( b.p. 60-80 ° ) to give the ketone ( VII ) , m.p. 114.5-116 ° ( Found : C , 59.1 ; H , 2.5 . C1H , FO requires C , 58 · 75 ; H , 2 · 5 ...
Page 3838
... give products resulting from the replacement of one or more vinylic fluorine atoms by trimethylsilyl groups , together with mercury and fluoro- trimethylsilane . Thus perfluorocyclobutene gives 1,3,3,4,4 - pentafluoro - 2 ...
... give products resulting from the replacement of one or more vinylic fluorine atoms by trimethylsilyl groups , together with mercury and fluoro- trimethylsilane . Thus perfluorocyclobutene gives 1,3,3,4,4 - pentafluoro - 2 ...
Page 3904
... give compound ( V ) or it may extract the chloro- substituent to give an ortho - substituted thiophenoxide ion and diethyl chloromalonate which could then react to give the same compound ( V ) . In support of this mechanism , the ...
... give compound ( V ) or it may extract the chloro- substituent to give an ortho - substituted thiophenoxide ion and diethyl chloromalonate which could then react to give the same compound ( V ) . In support of this mechanism , the ...
Contents
Organic chemistry | 3513 |
Partially fluorinated heterocyclic compounds Part IX The syntheses of 4567tetrafluorobenzobfuran | 3516 |
Reactions of cyclohexadienes Part XII Some dienamines and dimethyl acetylenedicarboxylate | 3517 |
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acetic acid acetic anhydride acetone alkyl Amer amine aqueous ethanol aromatic atom benzene benzene-light petroleum benzyl boiling boron tribromide bromide Calc carbonyl CH₂ CHCl3 Chem chloroform chromatography cm¯¹ cm¹ CO₂H compound condensation cooled crystallised decomp derivatives diazomethane dimer dimethyl dimethylformamide dioxan dried elution enol ergochrysin ester ethanol ether ethyl acetate EtOH evaporated extracted filtered Found gave give heated hydrogen chloride i.r. spectrum identical isolated isomers ketone log ɛ mass spectra methyl methylene mixed m.p. mixture myricanone n.m.r. spectrum nitrogen Nujol obtained olefinic oxidation petroleum Ph Ph Ph PhCH₂ phenolic potassium prepared prisms protons pyridine quinuclidine reaction refluxed requires residue ring room temperature S)-sulphoxide sclerotiorin signals singlet sodium hydrogen carbonate sodium hydroxide solid solution solvent stirred structure sulphoxide synthesis triethylamine vacuo W. B. Whalley washed yellow needles yield