Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 46
... activation since there is a large crystal field activation energy contribution for this electronic configuration for dissociative or for associ- ative reactions . Laidler's simple electrostatic approach forecasts an entropy of activation ...
... activation since there is a large crystal field activation energy contribution for this electronic configuration for dissociative or for associ- ative reactions . Laidler's simple electrostatic approach forecasts an entropy of activation ...
Page 251
Chemical Society (Great Britain). TABLE 6 Comparison of calculated activation energies of ion pair and semi - ion pair models with observed activation energies D ( R + F- ) E ( calc . ) • Values from J. A. Kerr , Chem . Rev. , 1966 , 66 ...
Chemical Society (Great Britain). TABLE 6 Comparison of calculated activation energies of ion pair and semi - ion pair models with observed activation energies D ( R + F- ) E ( calc . ) • Values from J. A. Kerr , Chem . Rev. , 1966 , 66 ...
Page 358
... Activation Energies . - From the oxidation rates at temperatures varying between 49-8 and 81-4 ° C the activation energies of the following reactions were calculated from the resulting Arrhenius plots and are listed in Table 7 ...
... Activation Energies . - From the oxidation rates at temperatures varying between 49-8 and 81-4 ° C the activation energies of the following reactions were calculated from the resulting Arrhenius plots and are listed in Table 7 ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield