Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 19
... exchange between the irradi- ated and observed proton sites at a rate faster than their spin - lattice relaxation time.17 Unlike several other -allyl systems 18 this is not a syn - anti exchange but an exchange of the ends of the ...
... exchange between the irradi- ated and observed proton sites at a rate faster than their spin - lattice relaxation time.17 Unlike several other -allyl systems 18 this is not a syn - anti exchange but an exchange of the ends of the ...
Page 225
... Exchange . In the model used here , involving a di- agonally blocked wave - function , intra - atomic exchange is included but interatomic exchange is neglected . The exchange terms referred to involve real orbitals . To determine the ...
... Exchange . In the model used here , involving a di- agonally blocked wave - function , intra - atomic exchange is included but interatomic exchange is neglected . The exchange terms referred to involve real orbitals . To determine the ...
Page 648
... Exchange . - The acid - catalysed exchange of oxygen between Co ( CO ) , and solvent water shows two kinetically distinct types of oxygen in the complex . Six oxygen atoms exchange about 50 times more rapidly than the remaining six at ...
... Exchange . - The acid - catalysed exchange of oxygen between Co ( CO ) , and solvent water shows two kinetically distinct types of oxygen in the complex . Six oxygen atoms exchange about 50 times more rapidly than the remaining six at ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
Copyright | |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield