Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 415
... hexane . ( II ) Bistriphenylphosphine ( cinnamaldehyde ) platinum ( 0 ) . -Cinnamaldehyde ( 0-1 ml . ) was added to a solution of Pt ( PPh3 ) , ( 200 mg ) in a mixture of benzene ( 2 ml ) and diethyl ether ( 10 ml ) . Diethyl ether was ...
... hexane . ( II ) Bistriphenylphosphine ( cinnamaldehyde ) platinum ( 0 ) . -Cinnamaldehyde ( 0-1 ml . ) was added to a solution of Pt ( PPh3 ) , ( 200 mg ) in a mixture of benzene ( 2 ml ) and diethyl ether ( 10 ml ) . Diethyl ether was ...
Page 461
... hexane ( 20 ml ) a solution of bromine ( 42 mg , 0.26 mmole ) in hexane ( 20 ml ) was added dropwise at 0 ° . When i.r. monitoring showed that reaction was complete ( 10 min ) , the volume of the solution was reduced to 5 ml . and it ...
... hexane ( 20 ml ) a solution of bromine ( 42 mg , 0.26 mmole ) in hexane ( 20 ml ) was added dropwise at 0 ° . When i.r. monitoring showed that reaction was complete ( 10 min ) , the volume of the solution was reduced to 5 ml . and it ...
Page 462
... hexane ( 30 ml ) under nitrogen , when the yellow solution became deep orange during 15 min . Subsequent removal of solvent left a red crystalline mass , recrystallised from hexane at -78 ° as red needles of [ ( Me , Si ) Ru ( CO ) , I ] ...
... hexane ( 30 ml ) under nitrogen , when the yellow solution became deep orange during 15 min . Subsequent removal of solvent left a red crystalline mass , recrystallised from hexane at -78 ° as red needles of [ ( Me , Si ) Ru ( CO ) , I ] ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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¹H n.m.r. spectra absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¹ co-ordination cobalt(II complexes compound concentration crystal cyanide diethyl ether electron electronegativity energy equation ethanol experimental factors Figure filtered fluorides formation frequencies H₂O halide hexane hydrogen i.r. spectra imidazole Inorg intensity isomers k₁ kcal ligand measured methyl methylene mixture mmol modes mol-¹ molecular molecule nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters perovskite phosphine photolysis Phys planar plane platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahedral tetrahydrofuran thermal thorium vacuo values vibrations X-ray yellow yield