Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 225
... orbitals . To determine the importance of inter- and intra- atomic exchange terms to valence orbital sizes , calcula- tions were performed for SF , in which intra - atomic exchange was neglected and in which interatomic exchange was ...
... orbitals . To determine the importance of inter- and intra- atomic exchange terms to valence orbital sizes , calcula- tions were performed for SF , in which intra - atomic exchange was neglected and in which interatomic exchange was ...
Page 226
... orbital exponents SF . PF5 CIF3 Multi- Single- Multi- Single- Multi- Single- configur- configur- configur- configur- configur- configur- ational ational ational ational ational ational α38 2.06 1.93 1.80 1.65 2.39 2.22 a3p 1.71 1.64 ...
... orbital exponents SF . PF5 CIF3 Multi- Single- Multi- Single- Multi- Single- configur- configur- configur- configur- configur- configur- ational ational ational ational ational ational α38 2.06 1.93 1.80 1.65 2.39 2.22 a3p 1.71 1.64 ...
Page 666
... orbitals analysed in terms of their atomic - orbital components shown in Tables 3—5 . The electron - donor properties of the phosphines are as- sociated with their highest filled molecular orbitals ( ' lone- pair ' orbitals ) ...
... orbitals analysed in terms of their atomic - orbital components shown in Tables 3—5 . The electron - donor properties of the phosphines are as- sociated with their highest filled molecular orbitals ( ' lone- pair ' orbitals ) ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield