Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 225
... orbitals . The 3d orbital is the least affected . The very polarisable 3d orbitals should not be considered in such studies as this , without also taking into account variation in 3s and 3p orbital sizes . The contribution to the total ...
... orbitals . The 3d orbital is the least affected . The very polarisable 3d orbitals should not be considered in such studies as this , without also taking into account variation in 3s and 3p orbital sizes . The contribution to the total ...
Page 226
... orbital exponents SF . PF5 CIF3 Multi- Single- Multi- Single- Multi- Single- configur- configur- configur- configur- configur- configur- ational ational ational ational ational ational α38 2.06 1.93 1.80 1.65 2.39 2.22 a3p 1.71 1.64 ...
... orbital exponents SF . PF5 CIF3 Multi- Single- Multi- Single- Multi- Single- configur- configur- configur- configur- configur- configur- ational ational ational ational ational ational α38 2.06 1.93 1.80 1.65 2.39 2.22 a3p 1.71 1.64 ...
Page 666
... orbitals are predominantly fluorine 2p - non - bonding orbitals and have direct counterparts in PF3 . The re- maining orbitals , except the 9a1 - orbital which has a major borane o - component , are mainly localized on the phos- phine ...
... orbitals are predominantly fluorine 2p - non - bonding orbitals and have direct counterparts in PF3 . The re- maining orbitals , except the 9a1 - orbital which has a major borane o - component , are mainly localized on the phos- phine ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield