Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 329
... oxygen atoms . One possible explanation could be that mole- cular oxygen is removed by reaction with methyl radicals or nitric oxide . However , the reaction of methyl radicals with oxygen produces formaldehyde , 11 which was not found ...
... oxygen atoms . One possible explanation could be that mole- cular oxygen is removed by reaction with methyl radicals or nitric oxide . However , the reaction of methyl radicals with oxygen produces formaldehyde , 11 which was not found ...
Page 645
... oxygen between the trisoxalatocobaltate ( III ) anion and solvent water , obtained by use of oxygen - 18 , are reported . At 25 ° C , in the presence of 1 M - HCI , the carbonyl oxygen ex- changes ca. 50 times faster than the bridging ...
... oxygen between the trisoxalatocobaltate ( III ) anion and solvent water , obtained by use of oxygen - 18 , are reported . At 25 ° C , in the presence of 1 M - HCI , the carbonyl oxygen ex- changes ca. 50 times faster than the bridging ...
Page 648
... Oxygen Exchange . - The acid - catalysed exchange of oxygen between Co ( CO ) , and solvent water shows two kinetically distinct types of oxygen in the complex . Six oxygen atoms exchange about 50 times more rapidly than the remaining ...
... Oxygen Exchange . - The acid - catalysed exchange of oxygen between Co ( CO ) , and solvent water shows two kinetically distinct types of oxygen in the complex . Six oxygen atoms exchange about 50 times more rapidly than the remaining ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
Copyright | |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield