Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 87
... plexes . Protactinium pentachloride or pentabromide ( 0.1 g ) was added to a 1 : 1 or 1 : 2 mole ratio of triphenylphos- phine oxide dissolved in anhydrous methyl cyanide or methylene dichloride ( 0 · 5 ml ) . The soluble 1 : 1 ...
... plexes . Protactinium pentachloride or pentabromide ( 0.1 g ) was added to a 1 : 1 or 1 : 2 mole ratio of triphenylphos- phine oxide dissolved in anhydrous methyl cyanide or methylene dichloride ( 0 · 5 ml ) . The soluble 1 : 1 ...
Page 376
... plexes seem to prefer to add on hydrogen chloride rather than protonate to give a cationic olefin complex . Possible steric crowding by the four cis - ligands in these six - co - ordinate iridium complexes prevents formation of a π ...
... plexes seem to prefer to add on hydrogen chloride rather than protonate to give a cationic olefin complex . Possible steric crowding by the four cis - ligands in these six - co - ordinate iridium complexes prevents formation of a π ...
Page 765
... plexes have been independently prepared by our route but erroneously formulated as dinitrito - derivatives.5 Our observation that nitric oxide does not react with the iridium dioxygen complexes IrX ( O2 ) ( CO ) ( APh 。) , cannot be ...
... plexes have been independently prepared by our route but erroneously formulated as dinitrito - derivatives.5 Our observation that nitric oxide does not react with the iridium dioxygen complexes IrX ( O2 ) ( CO ) ( APh 。) , cannot be ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
Copyright | |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield