Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 648
... solvent water.3,8 It is similar , however , to that shown by Rh ( C2O4 ) 38 . In this anion at 25 ° C , the carbonyl oxygens undergo acid - catalysed exchange with solvent water about 60 times as fast as the metal - ligand bridging ...
... solvent water.3,8 It is similar , however , to that shown by Rh ( C2O4 ) 38 . In this anion at 25 ° C , the carbonyl oxygens undergo acid - catalysed exchange with solvent water about 60 times as fast as the metal - ligand bridging ...
Page 769
... Solvent ( h ) ( g ) Reagent s - TCE 3.5 58.0 Analytical s - TCE 4.5 56.5 Analytical s - TCE 10.0 41.5 3.5 8 Reagent PhCl Analytical PhCl 27.0 20.0 51.0 57.7 38.0 92 1.5 3 49.5 97 37.0 64 20.7 36 gives the results of reactions using ...
... Solvent ( h ) ( g ) Reagent s - TCE 3.5 58.0 Analytical s - TCE 4.5 56.5 Analytical s - TCE 10.0 41.5 3.5 8 Reagent PhCl Analytical PhCl 27.0 20.0 51.0 57.7 38.0 92 1.5 3 49.5 97 37.0 64 20.7 36 gives the results of reactions using ...
Page 770
... solvent . Meanwhile the key to repro- ducibility of results in the reaction of PCI , and NH4Cl is to use solvent drawn from the same source each time , and preferably unused solvent . Another aspect of the solvent is its volume and it ...
... solvent . Meanwhile the key to repro- ducibility of results in the reaction of PCI , and NH4Cl is to use solvent drawn from the same source each time , and preferably unused solvent . Another aspect of the solvent is its volume and it ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield