Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 393
... temperature - inde- pendent paramagnetism . Taking N ( x ) = 250 × 10-6 c.g.s.u. and Heft 3-4 B.M. for the high - spin form , equation ( 1 ) yields values of AE which vary with temperature , i.e. from 203 cm - 1 at 99 K to -103 cm - 1 ...
... temperature - inde- pendent paramagnetism . Taking N ( x ) = 250 × 10-6 c.g.s.u. and Heft 3-4 B.M. for the high - spin form , equation ( 1 ) yields values of AE which vary with temperature , i.e. from 203 cm - 1 at 99 K to -103 cm - 1 ...
Page 394
... temperature was taken equal to that of the chloro - complex at the same temperature , and the low - spin moment was taken equal to that obtained . from an extrapolation of the linear section of the x ' vs. 1 / T plot ( bromide ) again ...
... temperature was taken equal to that of the chloro - complex at the same temperature , and the low - spin moment was taken equal to that obtained . from an extrapolation of the linear section of the x ' vs. 1 / T plot ( bromide ) again ...
Page 798
... temperature was lowered from 300 to 77 K , indicating a low effective Debye temperature for iron in this compound . At all temperatures , in zero external magnetic field , the spectrum consisted of a quadrupole split pair of lines . The ...
... temperature was lowered from 300 to 77 K , indicating a low effective Debye temperature for iron in this compound . At all temperatures , in zero external magnetic field , the spectrum consisted of a quadrupole split pair of lines . The ...
Contents
Inorganic physical and theoretical chemistry | 1 |
Singlecrystal vibrational spectrum of tetrakisthioacetamido copper 1 chloride | 8 |
Allylic complexes of ruthenium | 16 |
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absorption acid Acta Cryst adduct Amer amine angles aqueous assigned ation bands benzene bond lengths boron boron trichloride calculated carbon atom carbonyl Chem chemical Chemistry chloride cm-¹ cm¯¹ cm¹ co-ordination cobalt(II complexes compounds concentration crystal cyanide diethyl ether electron energy equation ethanol ether experimental factors Figure filtered fluorides formation frequencies halide hydrogen i.r. spectra imidazole Inorg intensity ions isomers k₁ kcal ligand measured metal methyl methylene mixture mmol modes mol-¹ molecular molecule n.m.r. spectra nickel nitrogen Nujol observed obtained olefin orbital oxide oxygen atoms parameters peaks perovskite phosphine photolysis Phys platinum plexes prepared present protons pyridine radical Raman rate constants ratio reaction resonance room temperature sample similar sodium solid solution solvent species spectra spectrum structure studies symmetry Table tetrahydrofuran thermal thorium triplet vacuo values vibrations X-ray yellow yield