Quarterly Journal of the Chemical Society of London, Volume 19 |
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Page 3079
... isomer predominates . As will be shown later , M.O. calculations also predict the cis- isomer to be more stable than the trans - isomer in such compounds . ( iii ) When R1 is a methyl group instead of formyl hydrogen ( and R2 = Me ) ...
... isomer predominates . As will be shown later , M.O. calculations also predict the cis- isomer to be more stable than the trans - isomer in such compounds . ( iii ) When R1 is a methyl group instead of formyl hydrogen ( and R2 = Me ) ...
Page 3081
... isomer with increase in temperature . Since the dissociation of the cis - dimers should occur with increase in temperature , the observed increase in the trans- isomer with temperature is significant . By an examin- ation of the ...
... isomer with increase in temperature . Since the dissociation of the cis - dimers should occur with increase in temperature , the observed increase in the trans- isomer with temperature is significant . By an examin- ation of the ...
Page 3284
... isomer is the more stable but for reasons which are explained below we believe isomer ( III ) to be the form of lowest enthalpy . The variations in the ( Hg - H ) coupling constants can be interpreted similarly if the simplifying ...
... isomer is the more stable but for reasons which are explained below we believe isomer ( III ) to be the form of lowest enthalpy . The variations in the ( Hg - H ) coupling constants can be interpreted similarly if the simplifying ...
Contents
Inorganic physical and theoretical chemistry | 2963 |
Structure of radicals produced by yradiolysis Part I 3Methylpentyl 2methylpentyl and isopentyl | 2971 |
Structure and conformational analysis of coordination complexes Part II XRay crystal structure of cis | 2981 |
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absorption acetate acetonitrile acid Acta Cryst adducts Amer angles anion aqueous assigned axis band benzene bond lengths calculated carbon carbonyl cation chelate Chem Chemical chemical shifts Chemistry chloride cm-¹ cm¹ co-ordination cobalt complexes compounds copper atom copper(II correlation coupling crystal derivatives deuterium diethyl ether doublet electron energy equation experimental Figure formation frequency H₂O halide hydrogen hydrogen bonding i.r. spectra indium(III Inorg intensity interaction iron(III isomer kinetic ligand magnetic metal methanol methyl mixture mmol mmoles molecular molecule n.m.r. spectra nitrogen Nujol observed obtained orbital oxide oxygen parameters phosphite Phys plane prepared present protons pyridine Raman reaction resonance rhodium ring room temperature salts shift shows similar SnCl sodium solid solution solvent space group species spectra spectrum stretching mode structure studies symmetry Table trans transition triphenylphosphine values vanadium(IV vibrational yellow