Quarterly Journal of the Chemical Society of London, Volume 19 |
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Page 2974
... values of K are 1-1 , 8-0 , and 20-0 . The approximation K = ∞ is surprisingly good , and for any value of K greater than about 8 will yield values of the rate constant to within 1 % up to 25 % reaction and to within 0-2 % up to 15 ...
... values of K are 1-1 , 8-0 , and 20-0 . The approximation K = ∞ is surprisingly good , and for any value of K greater than about 8 will yield values of the rate constant to within 1 % up to 25 % reaction and to within 0-2 % up to 15 ...
Page 3167
... Values . - From the measured signs , p.q.s. values for many ligands can now be derived , by use of the approach and assumptions outlined earlier.3 We take the reference p.q.s. value of chloride to be -0.30 mm / s1 , * and recall that ...
... Values . - From the measured signs , p.q.s. values for many ligands can now be derived , by use of the approach and assumptions outlined earlier.3 We take the reference p.q.s. value of chloride to be -0.30 mm / s1 , * and recall that ...
Page 3375
... value to fit Au , equally good agreement between observed and calculated values is obtained , though in no case is the agreement perfect . For p in the range 2000 cm - 1 > P2 > 1000 cm1 the value of 0 for fitting Au at various ...
... value to fit Au , equally good agreement between observed and calculated values is obtained , though in no case is the agreement perfect . For p in the range 2000 cm - 1 > P2 > 1000 cm1 the value of 0 for fitting Au at various ...
Contents
Inorganic physical and theoretical chemistry | 2963 |
Structure of radicals produced by yradiolysis Part I 3Methylpentyl 2methylpentyl and isopentyl | 2971 |
Structure and conformational analysis of coordination complexes Part II XRay crystal structure of cis | 2981 |
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absorption acetate acetonitrile acid Acta Cryst adducts Amer angles anion aqueous assigned axis band benzene bond lengths calculated carbon carbonyl cation chelate Chem Chemical chemical shifts Chemistry chloride cm-¹ cm¹ co-ordination cobalt complexes compounds copper atom copper(II correlation coupling crystal derivatives deuterium diethyl ether doublet electron energy equation experimental Figure formation frequency H₂O halide hydrogen hydrogen bonding i.r. spectra indium(III Inorg intensity interaction iron(III isomer kinetic ligand magnetic metal methanol methyl mixture mmol mmoles molecular molecule n.m.r. spectra nitrogen Nujol observed obtained orbital oxide oxygen parameters phosphite Phys plane prepared present protons pyridine Raman reaction resonance rhodium ring room temperature salts shift shows similar SnCl sodium solid solution solvent space group species spectra spectrum stretching mode structure studies symmetry Table trans transition triphenylphosphine values vanadium(IV vibrational yellow