Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1610
... [ Table 1 , ( a ) and ( b ) ] . Variation of the concentration of acid did not greatly affect the reaction rate ; Table 1 ( c ) shows that a ten - fold increase in [ H2SO ] may increase the rate by 20-50 % . The effect of deuterium ...
... [ Table 1 , ( a ) and ( b ) ] . Variation of the concentration of acid did not greatly affect the reaction rate ; Table 1 ( c ) shows that a ten - fold increase in [ H2SO ] may increase the rate by 20-50 % . The effect of deuterium ...
Page 1719
... ( Table 3 ) . On the basis of eqn . ( 1 ) , and using the proportionality between k and the hydroxide ion concentration ( Table 2 ) to calculate the appropriate value of k , it is possible to predict the expected reaction curves of Table ...
... ( Table 3 ) . On the basis of eqn . ( 1 ) , and using the proportionality between k and the hydroxide ion concentration ( Table 2 ) to calculate the appropriate value of k , it is possible to predict the expected reaction curves of Table ...
Page 1932
... ( Table 2 ) . The energy of activation is similar in magnitude to that found for amides 4 and for mixed anhydrides 2,5 of phosphoric acid . After passing through TABLE 2 . First - order rate constants for hydrolysis at pH 4 . Temp . ( ° c ) ...
... ( Table 2 ) . The energy of activation is similar in magnitude to that found for amides 4 and for mixed anhydrides 2,5 of phosphoric acid . After passing through TABLE 2 . First - order rate constants for hydrolysis at pH 4 . Temp . ( ° c ) ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield