Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
From inside the book
Results 1-3 of 83
Page 1341
... amine molecule is introduced ( which may be the original or additional amine ) as a kinetic entity for proton abstraction , the rate of the reaction v , by the concerted process A is given by eqn . ( 1 ) . Pathway B corresponds to eqn ...
... amine molecule is introduced ( which may be the original or additional amine ) as a kinetic entity for proton abstraction , the rate of the reaction v , by the concerted process A is given by eqn . ( 1 ) . Pathway B corresponds to eqn ...
Page 1342
... [ Amine ] » k_k1 + k_kg [ H + ] , and again kexp . k1 . Pathways A and B can also be rejected immediately , by taking ... amine , HCI ) 2 Me2N ( + amine ) , k , Pathway A CN CN + Me2N = ( II ) H ( o - complex ) k - s CN C = C ( CN ) 2 C ...
... [ Amine ] » k_k1 + k_kg [ H + ] , and again kexp . k1 . Pathways A and B can also be rejected immediately , by taking ... amine , HCI ) 2 Me2N ( + amine ) , k , Pathway A CN CN + Me2N = ( II ) H ( o - complex ) k - s CN C = C ( CN ) 2 C ...
Page 1352
... amine concentrations , which is much higher than that used in the kinetic runs , the concentration of the o ... amine , and which include therefore both the effect of the original N - methylaniline and that of the added amine , were ...
... amine concentrations , which is much higher than that used in the kinetic runs , the concentration of the o ... amine , and which include therefore both the effect of the original N - methylaniline and that of the added amine , were ...
Other editions - View all
Common terms and phrases
1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield