Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1350
... increase with increase in the amine concentration , although the increase was somewhat smaller than in the → o - reaction ( Table 4 ) . The increase in the rates is linear with increase in the amine concentrations TABLE 2 . First ...
... increase with increase in the amine concentration , although the increase was somewhat smaller than in the → o - reaction ( Table 4 ) . The increase in the rates is linear with increase in the amine concentrations TABLE 2 . First ...
Page 1356
... increase of the rate coefficient with the increase in the amine concentration in the N - methylaniline - tetracyanoethylene system . A constancy in the rate coefficients , as found experimentally for the dimethylaniline ...
... increase of the rate coefficient with the increase in the amine concentration in the N - methylaniline - tetracyanoethylene system . A constancy in the rate coefficients , as found experimentally for the dimethylaniline ...
Page 1367
... increase of the rates with the increase in the dielectric constant was ascribed to the increase of the equilibrium constant which some- what overcompensates the decrease in the rate of the elimination process . This explan- ation is in ...
... increase of the rates with the increase in the dielectric constant was ascribed to the increase of the equilibrium constant which some- what overcompensates the decrease in the rate of the elimination process . This explan- ation is in ...
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Common terms and phrases
1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield