Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1489
... manganese ( 11 ) species . With the oxidation of malonic acid , however , a retardation of the reaction according to equation ( A ) , is affected by increasing the prevailing manganese ( II ) concentration . 1 ( A [ Mn ] / At ) = a + b [ Mn ] ...
... manganese ( 11 ) species . With the oxidation of malonic acid , however , a retardation of the reaction according to equation ( A ) , is affected by increasing the prevailing manganese ( II ) concentration . 1 ( A [ Mn ] / At ) = a + b [ Mn ] ...
Page 1491
... manganese ( III ) pyrophosphate in the oxidation by manganese ( III ) sulphate indicates that both oxidations proceed by a common mechanism . Table 2 shows that a malonic acid- manganese ( III ) complex is again involved . 7 Two points ...
... manganese ( III ) pyrophosphate in the oxidation by manganese ( III ) sulphate indicates that both oxidations proceed by a common mechanism . Table 2 shows that a malonic acid- manganese ( III ) complex is again involved . 7 Two points ...
Page 1492
... manganese ( III ) sulphate oxidations enable us to compare third - order rate constants at 30 ° , the temperature employed by Drummond and Waters , after extrapolation of both sets of data of the manganese ( III ) oxidations to zero value ...
... manganese ( III ) sulphate oxidations enable us to compare third - order rate constants at 30 ° , the temperature employed by Drummond and Waters , after extrapolation of both sets of data of the manganese ( III ) oxidations to zero value ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield