Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1344
... nucleophilic step ( the " carbon basicity " ) . 1,26 This is not readily measurable in nucleophilic attacks of this type , as the carbanions first formed enter into various types of rapid reactions . However , the existence of such an ...
... nucleophilic step ( the " carbon basicity " ) . 1,26 This is not readily measurable in nucleophilic attacks of this type , as the carbanions first formed enter into various types of rapid reactions . However , the existence of such an ...
Page 1360
... nucleophilic reactions on carbon - carbon double bonds . IN nucleophilic reactions on carbon - carbon double bonds the initially formed carbanion or zwitterion may enter a variety of different pathways , resulting in addition ...
... nucleophilic reactions on carbon - carbon double bonds . IN nucleophilic reactions on carbon - carbon double bonds the initially formed carbanion or zwitterion may enter a variety of different pathways , resulting in addition ...
Page 1366
... nucleophilic attack . Comparison of the positive e values with those for other nucleophilic attcks on double bonds shows them to be higher than that for the barbiturate anion - ẞ - nitrostyrene system ( p = 0.74 ) , 26 but comparable to ...
... nucleophilic attack . Comparison of the positive e values with those for other nucleophilic attcks on double bonds shows them to be higher than that for the barbiturate anion - ẞ - nitrostyrene system ( p = 0.74 ) , 26 but comparable to ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield