Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1222
... sulphide were the sulphoxide and the a - benzoyloxy - sulphide : RS CH2R ' RSO CH2R ' + RS • CHR ' • O • COPh t - Butyl methyl sulphide and benzoyl peroxide at 18 ° gave benzoic acid ( 48 % ) and benzoic anhydride , together with t ...
... sulphide were the sulphoxide and the a - benzoyloxy - sulphide : RS CH2R ' RSO CH2R ' + RS • CHR ' • O • COPh t - Butyl methyl sulphide and benzoyl peroxide at 18 ° gave benzoic acid ( 48 % ) and benzoic anhydride , together with t ...
Page 1251
... sulphide . Rotations for the halides [ EtSNa ] . Max . value from Halide αD 20 [ Halide ] . ap for sulphide this work Chloride Bromide -29-36 ° 3.9 1 13.0 ° 32.4 ° -39.6 10.6 1 12.78 44.5 -37.67 4.1 1 12.26 44.1 Iodide -60-2 8 : 1 13.46 ...
... sulphide . Rotations for the halides [ EtSNa ] . Max . value from Halide αD 20 [ Halide ] . ap for sulphide this work Chloride Bromide -29-36 ° 3.9 1 13.0 ° 32.4 ° -39.6 10.6 1 12.78 44.5 -37.67 4.1 1 12.26 44.1 Iodide -60-2 8 : 1 13.46 ...
Page 1639
... sulphide as yellow needles ( 5.4 g . ) ( from alcohol ) , m . p . 46.5 ° ( Found : C , 69-2 ; H , 4 · 7 ; N , 4 · 5 . C17H13NOS requires C , 69-1 ; H , 4 · 4 ; N , 4 · 7 % ) · 6 - Methyl - 9 - thia - 1,2 - benzofluorene ( II ; R = Me ) ...
... sulphide as yellow needles ( 5.4 g . ) ( from alcohol ) , m . p . 46.5 ° ( Found : C , 69-2 ; H , 4 · 7 ; N , 4 · 5 . C17H13NOS requires C , 69-1 ; H , 4 · 4 ; N , 4 · 7 % ) · 6 - Methyl - 9 - thia - 1,2 - benzofluorene ( II ; R = Me ) ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon Chem chloride chloroform CHPh chromatography cm.¹ complex compounds concentration crystallised cyanohydrin derivative diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated EXPERIMENTAL extracted formation formed Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum isomers k₁ k₂ kcal ketone kinetic ligand magnesium manganese(III methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical oxaloacetic acid oxidation peaks peroxide petroleum b. p. phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients reaction reflux requires residue room temperature rotation shown silanes sodium solution solvent spectra structure substituted sulphide sulphuric Table tetracyanoethylene titration tricyanovinyl values yield