Journal of the Chemical Society, Part 4The Society., 1949 |
From inside the book
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Page 2603
... aluminium chloride , but with the bromide and a whole range of related halides , from which AH is obtained . We have also applied in a few cases a new but somewhat laborious analysis of calorimetric data leading to an estimate of AG ...
... aluminium chloride , but with the bromide and a whole range of related halides , from which AH is obtained . We have also applied in a few cases a new but somewhat laborious analysis of calorimetric data leading to an estimate of AG ...
Page 2612
... aluminium chloride we can calculate a new set of equilibrium constants based on the total free - energy change . Equation ( 1 ) is used without including the specific heat terms , and corresponding yields are obtained as follows ...
... aluminium chloride we can calculate a new set of equilibrium constants based on the total free - energy change . Equation ( 1 ) is used without including the specific heat terms , and corresponding yields are obtained as follows ...
Page 2616
... aluminium chloride , the heat of formation as measured by us being about 8 kcals./mole of AICI ,. Since the heat of formation of the complex between aluminium chloride and benzaldehyde is 24-7 kcals . , then neglecting entropy ...
... aluminium chloride , the heat of formation as measured by us being about 8 kcals./mole of AICI ,. Since the heat of formation of the complex between aluminium chloride and benzaldehyde is 24-7 kcals . , then neglecting entropy ...
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Common terms and phrases
absorption acetic acid acetic anhydride acetone added alcohol alkaline aluminium chloride aluminium iodide Amer amine ammonia aqueous sodium atom benzaldehyde benzene boiling bond bromide bromine trifluoride Calc carbon CHâ‚‚ Chem chloroform colourless needles compound concentrated condensation containing cooled crystallised crystals D.Sc decomp decomposition derivatives diazotised dilute dioxan dissolved distilled dried ester ethanol ethyl alcohol extracted with ether filtered filtrate formation formed Found fraction gave Grignard reagent halide heated under reflux hydrochloric acid hydrogen chloride hydrolysis iodide iodine ions isolated ketone light petroleum b. p. liquid method methyl methyl iodide minutes mixture molecule nitrate nitrogen obtained oxidation phenol picrate potassium precipitate prepared prisms pyridine reaction reagent recrystallised from ethanol reduced pressure removed requires residue room temperature salt separated sodium hydroxide solid soluble solution solvent sulphate sulphone sulphuric acid synthesis Table tube values washed yield