Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1374
... dissociation constants found are given in Table 1 . TABLE 1 . Titration dissociation constants of oxaloacetic acid at 25 ° and I ~ 0 · 1 . al All solutions were initially 40 ml . 0 · 1м - KCl to which weighed amounts of solid ...
... dissociation constants found are given in Table 1 . TABLE 1 . Titration dissociation constants of oxaloacetic acid at 25 ° and I ~ 0 · 1 . al All solutions were initially 40 ml . 0 · 1м - KCl to which weighed amounts of solid ...
Page 1378
... dissociation constants Kalk ' , Ka2k ' , Ka1E ' , and Ka2E ' from the concen- trations of the relevant species . Values for the second tautomeric equilibrium constant and the first and second dissociation constants of the keto and enol ...
... dissociation constants Kalk ' , Ka2k ' , Ka1E ' , and Ka2E ' from the concen- trations of the relevant species . Values for the second tautomeric equilibrium constant and the first and second dissociation constants of the keto and enol ...
Page 1379
Chemical Society (Great Britain). TABLE 5 . Summary of the acid dissociation constants and tautomeric equilibrium constants of the keto and enol isomers of oxaloacetic acid at 25 ° and I ~ 0.1 . PKalk ' 2.24 s.d. pKa2k ' 3.90 PKale 1.89 ...
Chemical Society (Great Britain). TABLE 5 . Summary of the acid dissociation constants and tautomeric equilibrium constants of the keto and enol isomers of oxaloacetic acid at 25 ° and I ~ 0.1 . PKalk ' 2.24 s.d. pKa2k ' 3.90 PKale 1.89 ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon carboxyl Chem chloroform chromatography complex compounds concentration correlation crystallised cyclopropane derived diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether experimental extracted fluorine formation Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum ionisation isomers k₁ k₂ kcal kinetic ligand methanolysis mixed m. p. mixture mmoles mole mole-¹ molecular molecules nitrogen nucleophilic o-complex obtained oleyl alcohol optical orbitals oxaloacetic acid oxidation oxygen peak phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients rate constants reaction reflux requires residue rotation shown similar sodium solution solvent spectra structure substituted sulphide t-butyl methyl t-butyl peroxide Table tetracyanoethylene titration toluene-p-sulphonate values yield