Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1683
... rate constants under similar experimental conditions , and at 275 ° found k2 / k1 = 1 · 41 which corresponds well with the value ( 1 · 35 ) obtained from our Arrhenius plot . Comparison of Reactivities of Sodium and Potassium Atoms ...
... rate constants under similar experimental conditions , and at 275 ° found k2 / k1 = 1 · 41 which corresponds well with the value ( 1 · 35 ) obtained from our Arrhenius plot . Comparison of Reactivities of Sodium and Potassium Atoms ...
Page 1684
... rate constants for these reactants was obtained when potassium was replaced by sodium . Furthermore , since it is probable that the shapes of the energy surfaces and the resonance energies in the activated state will be different for ...
... rate constants for these reactants was obtained when potassium was replaced by sodium . Furthermore , since it is probable that the shapes of the energy surfaces and the resonance energies in the activated state will be different for ...
Page 2376
... rate constants were obtained from the semi - logarithmic plots of log10 ( V∞ — Vt ) against time , where V , is the titre of thorium nitate consumed when the reaction is stopped at time t . In view of the long half - life of the ...
... rate constants were obtained from the semi - logarithmic plots of log10 ( V∞ — Vt ) against time , where V , is the titre of thorium nitate consumed when the reaction is stopped at time t . In view of the long half - life of the ...
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1-methylheptyl 1-phenylethyl bromide absorption acetic acid acetone acetonitrile adducts alcohol Amer amine anhydride aniline aqueous atom benzene bond Calc calculated carbon carboxyl Chem chloroform chromatography complex compounds concentration correlation crystallised cyclopropane derived diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether experimental extracted fluorine formation Found fraction gave H₂O halides hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum ionisation isomers k₁ k₂ kcal kinetic ligand methanolysis mixed m. p. mixture mmoles mole mole-¹ molecular molecules nitrogen nucleophilic o-complex obtained oleyl alcohol optical orbitals oxaloacetic acid oxidation oxygen peak phenols phosphate phosphine picryl potassium prepared proton pyridine rate coefficients rate constants reaction reflux requires residue rotation shown similar sodium solution solvent spectra structure substituted sulphide t-butyl methyl t-butyl peroxide Table tetracyanoethylene titration toluene-p-sulphonate values yield