Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1027
... acid ( I ) AS ° ( cal . mole - 1 deg . - 1 ) -12.4 - 11.7 - 10.9 +0.37 -10-2 this description in accounting for the position of certain ortho - substituted acids in the order of acid strengths.1 However , in the use of arguments based upon ...
... acid ( I ) AS ° ( cal . mole - 1 deg . - 1 ) -12.4 - 11.7 - 10.9 +0.37 -10-2 this description in accounting for the position of certain ortho - substituted acids in the order of acid strengths.1 However , in the use of arguments based upon ...
Page 1028
... acids listed in Table 5 for which data are available the AH values TABLE 5 Thermodynamic data for meta - substituted benzoic acids at 298.15 ° K AG ° ΔΗ AS ° ( cal . deg . - 1 Acid ( cal . mole - 1 ) mole - 1 ) Ref . m - Cyanobenzoic + ...
... acids listed in Table 5 for which data are available the AH values TABLE 5 Thermodynamic data for meta - substituted benzoic acids at 298.15 ° K AG ° ΔΗ AS ° ( cal . deg . - 1 Acid ( cal . mole - 1 ) mole - 1 ) Ref . m - Cyanobenzoic + ...
Page 1426
... acid ( final concentration . 9-6м ) to a solution of the complex in Iм - acid an initial decrease in absorption is observed , followed by an in- crease as the bischloro - complex is formed ( Figure 2 ) . We note also that the initial ...
... acid ( final concentration . 9-6м ) to a solution of the complex in Iм - acid an initial decrease in absorption is observed , followed by an in- crease as the bischloro - complex is formed ( Figure 2 ) . We note also that the initial ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
J ROBINSON and C H L KENNARD | 1008 |
Nearestneighbour model for transfer of electronic excitation energy | 1016 |
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absorption acid Acta adducts Amer anion aqueous assigned atoms band benzene bond calculated cancrinite carbon cation Chem chemical chemical shifts Chemistry chloride cm.¹ co-ordination cobalt(II complex compounds concentration configuration crystals density effect electron energy enthalpy equation equilibrium ethanol experimental Figure fluorine formation frequency H₂O hydrogen i.r. spectrum increase Inorg intensity interaction iron(II k₁ ligand linear magnetic measured metal methaemoglobins method methyl mixture modes mole mole-¹ molecular molecule n.m.r. spectra niobium nitrogen Nujol observed obtained orbitals oxidation oxygen parameters peak perchlorate perchloric acid phenyl phosphine phosphorus Phys potassium prepared present proton pyridine radical Raman rate constant reaction resonance ring room temperature salt sample shift shown sodalite sodium solid solution solvent species spectra structure studied sulphur symmetry Table thiocyanate tion trans tributyl phosphate triphenylphosphine values vanadium(IV vibrations X-ray zeolite