Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1187
... constants may be expressed in several other ways . The hydrolysis constant given is a mixed constant , and must be multiplied by the activity coefficient of the hydr- constants can be multiplied by 0.1 to give the corresponding constants ...
... constants may be expressed in several other ways . The hydrolysis constant given is a mixed constant , and must be multiplied by the activity coefficient of the hydr- constants can be multiplied by 0.1 to give the corresponding constants ...
Page 1306
... constant was appreciably lower 10 * k ( sec.1 ) " teta " 120 80- 20 40 1 1 1 8 10 12 · [ H2SO11 ( M ) 0 10k ( sec - 1 ) " cyclam " FIGURE Variation of first - order rate constant with sulphuric acid concentration , at -7.5 ° , for : ( O ) ...
... constant was appreciably lower 10 * k ( sec.1 ) " teta " 120 80- 20 40 1 1 1 8 10 12 · [ H2SO11 ( M ) 0 10k ( sec - 1 ) " cyclam " FIGURE Variation of first - order rate constant with sulphuric acid concentration , at -7.5 ° , for : ( O ) ...
Page 1363
... constant matrix have been evaluated for some linear XYZ molecules as a function of the off - diagonal element kxx , xz . This is used to provide a basis for the comparison of bond strengths in related molecules . The treatment is ...
... constant matrix have been evaluated for some linear XYZ molecules as a function of the off - diagonal element kxx , xz . This is used to provide a basis for the comparison of bond strengths in related molecules . The treatment is ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
J ROBINSON and C H L KENNARD | 1008 |
Nearestneighbour model for transfer of electronic excitation energy | 1016 |
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absorption acid Acta adducts Amer anion aqueous assigned atoms band benzene bond calculated cancrinite carbon cation Chem chemical chemical shifts Chemistry chloride cm.¹ co-ordination cobalt(II complex compounds concentration configuration crystals density effect electron energy enthalpy equation equilibrium ethanol experimental Figure fluorine formation frequency H₂O hydrogen i.r. spectrum increase Inorg intensity interaction iron(II k₁ ligand linear magnetic measured metal methaemoglobins method methyl mixture modes mole mole-¹ molecular molecule n.m.r. spectra niobium nitrogen Nujol observed obtained orbitals oxidation oxygen parameters peak perchlorate perchloric acid phenyl phosphine phosphorus Phys potassium prepared present proton pyridine radical Raman rate constant reaction resonance ring room temperature salt sample shift shown sodalite sodium solid solution solvent species spectra structure studied sulphur symmetry Table thiocyanate tion trans tributyl phosphate triphenylphosphine values vanadium(IV vibrations X-ray zeolite