Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1305
... corresponding to complete protonation were observed . However , as the acid concentration increases still further the rate of hydrolysis decreases ; this is in marked contrast to the behaviour of the azido - systems studied earlier.1 ...
... corresponding to complete protonation were observed . However , as the acid concentration increases still further the rate of hydrolysis decreases ; this is in marked contrast to the behaviour of the azido - systems studied earlier.1 ...
Page 1582
... corresponding plot for ob- taining from these K , values the value of K , for the formation of Co ( HY ) ' NCS is shown in Figure 3 , together ( 803 - ( Eobs 20 10 5 1 15 B 10-3 ( Eobs - 02 / [ H + ] ( 1. mole - 1 ) FIGURE 2 Plots for ...
... corresponding plot for ob- taining from these K , values the value of K , for the formation of Co ( HY ) ' NCS is shown in Figure 3 , together ( 803 - ( Eobs 20 10 5 1 15 B 10-3 ( Eobs - 02 / [ H + ] ( 1. mole - 1 ) FIGURE 2 Plots for ...
Page 1585
... corresponding stability constants K = [ ML ] / [ M ] [ L ] for the addition of the unidentate ligand L to the corresponding aquo- cation . For example , the value obtained for NH , + Co11 ( EDTA ) 2 = Сo " ( EDTA ) NH , 2 is K2 = 120 1 ...
... corresponding stability constants K = [ ML ] / [ M ] [ L ] for the addition of the unidentate ligand L to the corresponding aquo- cation . For example , the value obtained for NH , + Co11 ( EDTA ) 2 = Сo " ( EDTA ) NH , 2 is K2 = 120 1 ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
J ROBINSON and C H L KENNARD | 1008 |
Nearestneighbour model for transfer of electronic excitation energy | 1016 |
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absorption acid Acta adducts Amer anion aqueous assigned atoms band benzene bond calculated cancrinite carbon cation Chem chemical chemical shifts Chemistry chloride cm.¹ co-ordination cobalt(II complex compounds concentration configuration crystals density effect electron energy enthalpy equation equilibrium ethanol experimental Figure fluorine formation frequency H₂O hydrogen i.r. spectrum increase Inorg intensity interaction iron(II k₁ ligand linear magnetic measured metal methaemoglobins method methyl mixture modes mole mole-¹ molecular molecule n.m.r. spectra niobium nitrogen Nujol observed obtained orbitals oxidation oxygen parameters peak perchlorate perchloric acid phenyl phosphine phosphorus Phys potassium prepared present proton pyridine radical Raman rate constant reaction resonance ring room temperature salt sample shift shown sodalite sodium solid solution solvent species spectra structure studied sulphur symmetry Table thiocyanate tion trans tributyl phosphate triphenylphosphine values vanadium(IV vibrations X-ray zeolite