Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1126
... equation ( 2 ) in which is a constant and ( 2 ) ε = α1 - 1e - T / v v is a temperature characteristic of the solvent ( 219 ° K for water ) . Equation ( 1 ) then becomes equation ( 3 ) or ( 4 ) , with a a constant . AG = = = α AnRT In ...
... equation ( 2 ) in which is a constant and ( 2 ) ε = α1 - 1e - T / v v is a temperature characteristic of the solvent ( 219 ° K for water ) . Equation ( 1 ) then becomes equation ( 3 ) or ( 4 ) , with a a constant . AG = = = α AnRT In ...
Page 1296
... equation ( 8 ) . For example , k for the 1 - ethyl- propyl radical is calculated as in equation ( 9 ) ( it should be noted that the calculation is carried out separately for each alkyl group attached to the a - carbon atom ) , k = CH3 ...
... equation ( 8 ) . For example , k for the 1 - ethyl- propyl radical is calculated as in equation ( 9 ) ( it should be noted that the calculation is carried out separately for each alkyl group attached to the a - carbon atom ) , k = CH3 ...
Page 1375
... equation ( 15 ) . Equation ( 16 ) fits the 102 k1 ( sec . ) 4.8 3.6 F 2.4 1-2 나으 B 4 2.5 ± 0.1 × 103 1.2 mole - 2 sec . - 1 at 25 ° and μ = 5 · 00 . Equation ( 18 ) can also be deduced for the pseudo - first- order rate constant from ...
... equation ( 15 ) . Equation ( 16 ) fits the 102 k1 ( sec . ) 4.8 3.6 F 2.4 1-2 나으 B 4 2.5 ± 0.1 × 103 1.2 mole - 2 sec . - 1 at 25 ° and μ = 5 · 00 . Equation ( 18 ) can also be deduced for the pseudo - first- order rate constant from ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
J ROBINSON and C H L KENNARD | 1008 |
Nearestneighbour model for transfer of electronic excitation energy | 1016 |
Copyright | |
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absorption acid Acta adducts Amer anion aqueous assigned atoms band benzene bond calculated cancrinite carbon cation Chem chemical chemical shifts Chemistry chloride cm.¹ co-ordination cobalt(II complex compounds concentration configuration crystals density effect electron energy enthalpy equation equilibrium ethanol experimental Figure fluorine formation frequency H₂O hydrogen i.r. spectrum increase Inorg intensity interaction iron(II k₁ ligand linear magnetic measured metal methaemoglobins method methyl mixture modes mole mole-¹ molecular molecule n.m.r. spectra niobium nitrogen Nujol observed obtained orbitals oxidation oxygen parameters peak perchlorate perchloric acid phenyl phosphine phosphorus Phys potassium prepared present proton pyridine radical Raman rate constant reaction resonance ring room temperature salt sample shift shown sodalite sodium solid solution solvent species spectra structure studied sulphur symmetry Table thiocyanate tion trans tributyl phosphate triphenylphosphine values vanadium(IV vibrations X-ray zeolite